Hmm looks like you might have some permission issues. I think i can help you with that. http://pastebin.com/ Paste your PEX permissions.yml thing there. EDIT by Moderator: merged posts, please use the edit button instead of double posting.
I'm assuming you're using PlotMe (you didn't say)... What do you have for spawn-protection in your server.properties? Set it to 0. Note that this will affect other worlds, so you may want to protect their spawns with a plugin like WorldGuard.
http://pastebin.com/P9nN5Nmt i will try They dont have access to any thing! not even food EDIT by Moderator: merged posts, please use the edit button instead of double posting.
Are you putting them into creative mode? Are you using something like Multiverse? If so, post your Multiverse worlds.yml file. You've given us very little information. List your plugins.